no chance for spidey. not if he's written properly. he's the complete opposite of "warrior." i still maintain the stance that superman is also un worthy in this regard. i don't see muchuva chance for daredevil, either.
wolverine is interesting, and would probably fit. he has viking-like rage, and at least in some tellings, a militant background to add to his warrior persona. i don't know if he's the type of character, though, that the god's would favor, however.
wonder woman is a guarantee. as is captain america (which has already happened, correct?). i'd say batman would rank high enough, as well.